
2007/62/6-1 'Synroc', ceramic / steel, made by Australian Nuclear Science Technology Organisation, Sydney, New South Wales, Australia, 1984-2007
The disposal of nuclear waste has been a controversial issue for decades. Synroc is an innovative solution to dealing with the problem of the long term storage of nuclear wastes that contain radioactive isotopes with long half-lives. It was originally developed in 1978 by Australian geochemist Professor Ted Ringwood and his team at the Australian National University.
Synroc is an advanced ceramic made up of the same types of minerals that have held uranium and thorium naturally in the Earth’s crust for billions of years. Radioactive waste atoms displace some host atoms, and so are chemically bound into a mineral matrix similar to natural rock, held until their radioactivity levels have decayed away.
The original type of Synroc was 57% titanium dioxide (rutile, TiO2) with the minerals hollandite (BaAl2Ti6O16), zirconolite (CaZrTi2O7) and perovskite (CaTiO3). Nuclear waste materials are added to the mixed powdered minerals and the ceramic is formed by heat and high compression. The Synroc is then placed in steel canisters.

91/23 Artificial Rock, Models (4), Synroc Manufacture, Australian Nuclear Science and Technology, Australia, 1990. Collection Powerhouse Museum
The original type of Synroc was intended mainly for the storage of liquid high level wastes from the reprocessing of light water reactor fuel. However, many countries did not reprocess this type of fuel; those that did had already chosen borosilicate glass as the storage medium because it was the most technically mature technology. This made it difficult to market Synroc, even though it was demonstrated to have superior waste storage properties. Unlike borosilicate glass, which is amorphous, Synroc incorporates the radioactive waste into the crystal structure of its individual grains, reducing the possibility of the waste leaking out.
At the Australian government’s request, a Synroc study group was set up in 1989 to look at ways in which the product could be commercialised. This group was comprised of four Australian companies, BHP (now BHP Billiton), CRA (now Rio Tinto), Energy Resources of Australia (ERA) and Western Mining Corporation (now part of BHP Billiton), together with ANSTO (Australian Nuclear Science and Technology Organisation) and the Australian National University. This group has further developed Synroc technology, resulting in a variety of ceramic and glass-ceramic Synroc formulations designed to cope with a diverse range of radioactive waste types, particularly those resulting from the construction of nuclear weapons.

91/22 Synthetic Rock, (4), Synroc Raw Materials, Australian Nuclear Science and Technology Organisation, Australia, 1990 Collection: Powerhouse Museum
In the late 90s the US Department of Energy selected Synroc for its plutonium immobilisation program, designed to lock up surplus plutonium from the US and Russian nuclear weapons programs. The immobilisation program was later dropped for political reasons. In 2005, the Synroc process was chosen for a multi-million dollar demonstration contract to eliminate five tonnes of plutonium-contaminated waste at British Nuclear Fuel’s Sellafield plant, on the northwest coast of England. Other projects aimed at cleaning up nuclear contamination are also considering the use of Synroc.
The museum has a number of Synroc samples in its collection, including samples of the original mineral components in powdered form, cutaway discs of Synroc material and complete simulated discs of material stacked in a waste container. Some of these samples can be seen on display in the Success and Innovation and Nuclear Matters exhibitions. One also features in Science Underground, curator-led tours of our basement store during Ultimo Science Festival, from 16-28 August 2011.



















